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Royal Society of Chemistry, Chemical Communications, 38(46), p. 7145

DOI: 10.1039/c0cc02440f

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On the relationship between structure and reaction rate in olefin ring-closing metathesis

Journal article published in 2010 by Ian W. Ashworth, Davide Carboni ORCID, Ian H. Hillier, David J. Nelson ORCID, Jonathan M. Percy, Giuseppe Rinaudo, Mark A. Vincent
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This paper is available in a repository.

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Abstract

In the RCM reactions of a series of simple alpha,omega-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic eta(2)-complex. ; 652KI Times Cited:0 Cited References Count:16