Published in
Royal Society of Chemistry, Catalysis Science & Technology, 2024
DOI: 10.1039/d3cy01446k
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Reversible transformation of sub-nanometer Ga-based clusters to isolated <sup>[4]</sup>Ga<sub>(4Si)</sub> sites creates active centers for propane dehydrogenation
Journal article published in 2024 by
Zixuan Chen 
,
Alexander I. Serykh ,
Agnieszka Kierzkowska ,
David Gajan,
Scott R. Docherty ,
Alexander V. Yakimov,
Paula M. Abdala ,
Christophe Copéret ,
Pierre Florian ,
Alexey Fedorov ,
Christoph R. Müller
,
Alexander I. Serykh ,
Agnieszka Kierzkowska ,
David Gajan,
Scott R. Docherty ,
Alexander V. Yakimov,
Paula M. Abdala ,
Christophe Copéret ,
Pierre Florian ,
Alexey Fedorov ,
Christoph R. Müller
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Abstract
This work describes how a propane dehydrogenation catalyst with isolated [4]Ga(4Si) sites can be prepared from silica-supported sub-nm gallia clusters containing [4]Ga(Ga) and [6]Ga(Ga) sites.