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Royal Society of Chemistry, Catalysis Science & Technology, 2024

DOI: 10.1039/d3cy01446k

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Reversible transformation of sub-nanometer Ga-based clusters to isolated <sup>[4]</sup>Ga<sub>(4Si)</sub> sites creates active centers for propane dehydrogenation

Journal article published in 2024 by Zixuan Chen ORCID, Alexander I. Serykh ORCID, Agnieszka Kierzkowska ORCID, David Gajan, Scott R. Docherty ORCID, Alexander V. Yakimov, Paula M. Abdala ORCID, Christophe Copéret ORCID, Pierre Florian ORCID, Alexey Fedorov ORCID, Christoph R. Müller ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

This work describes how a propane dehydrogenation catalyst with isolated [4]Ga(4Si) sites can be prepared from silica-supported sub-nm gallia clusters containing [4]Ga(Ga) and [6]Ga(Ga) sites.