Published in
Royal Society of Chemistry, Dalton Transactions, 18(50), p. 6126-6132, 2021
DOI: 10.1039/d1dt00096a
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Bond switching is responsible for nanoductility in zeolitic imidazolate framework glasses
Journal article published in 2021 by
Theany To 
,
Søren S. Sørensen ,
Yuanzheng Yue ,
Morten M. Smedskjaer
,
Søren S. Sørensen ,
Yuanzheng Yue ,
Morten M. Smedskjaer
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Abstract
The fracture mechanism of zeolitic imidazolate framework (ZIF) glasses is revealed to be associated with bond switching of organic linkers around central Zn nodes. The bond switching is more pronounced for ZIF glasses with smaller organic linkers.