Royal Society of Chemistry, Dalton Transactions, 22(51), p. 8855-8864, 2022
DOI: 10.1039/d2dt00998f
Full text: Unavailable
Sequential reduction of a uranium-azide through all the nitride steps is revealed. Experimentally determined U–U coupling in the diuranium(iv)–dinitride is shown byab initiocalculations to stem from the nitride bridges, not U–U bonding.