Published in
Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 34(11), p. 11460-11465, 2023
DOI: 10.1039/d3tc02088f
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Vapor-phase synthesis of low-valent metal–organic frameworks from metal carbonyl synthons
Journal article published in 2023 by
Carl Emil Andersen 
,
James Neill McPherson ,
Mónica Giménez-Marqués ,
Jingguo Li ,
Mariusz Kubus,
Sho Ito ,
Christian R. Göb ,
Sascha Ott ,
René Wugt Larsen ,
Guillermo Mínguez Espallargas ,
Kasper S. Pedersen
,
James Neill McPherson ,
Mónica Giménez-Marqués ,
Jingguo Li ,
Mariusz Kubus,
Sho Ito ,
Christian R. Göb ,
Sascha Ott ,
René Wugt Larsen ,
Guillermo Mínguez Espallargas ,
Kasper S. Pedersen
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Abstract
We demonstrate the facile vapor-phase synthesis of a novel, porous zero-valent metal–organic framework from the reaction between volatile M(CO)6 (M = Mo, W) and 4,4'-bipyridine precursors.