Published in
Royal Society of Chemistry, Dalton Transactions, 19(50), p. 6528-6538, 2021
DOI: 10.1039/d1dt00533b
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High-speed solid state fluorination of Nb<sub>2</sub>O<sub>5</sub> yields NbO<sub>2</sub>F and Nb<sub>3</sub>O<sub>7</sub>F with photocatalytic activity for oxygen evolution from water
Journal article published in 2021 by
Martin Alexander Lange,
Ibrahim Khan 
,
René Dören,
Muhammad Ashraf,
Ahsanulhaq Qurashi,
Leon Prädel,
Martin Panthöfer ,
Marcus von der Au,
Antje Cossmer,
Jens Pfeifer,
Björn Meermann ,
Mihail Mondeshki ,
Muhammad Nawaz Tahir,
Wolfgang Tremel
,
René Dören,
Muhammad Ashraf,
Ahsanulhaq Qurashi,
Leon Prädel,
Martin Panthöfer ,
Marcus von der Au,
Antje Cossmer,
Jens Pfeifer,
Björn Meermann ,
Mihail Mondeshki ,
Muhammad Nawaz Tahir,
Wolfgang Tremel
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Abstract
NbO2F and Nb3O7F were prepared by field-assisted chemistry from Nb2O5 and Teflon scrap in minutes, while chemistry requires days. NbO2F and Nb3O7F show high photocatalytic activity for water splitting, whereas the conventional products are inactive.