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Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 42(10), p. 15929-15940, 2022

DOI: 10.1039/d2tc02160a

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High-pressure synthesis, spin-glass behaviour, and magnetocaloric effects in Fe<sub>x</sub>Ti<sub>2</sub>S<sub>4</sub> heideite sulphides

Journal article published in 2022 by R. S. Silva Jr ORCID, J. Gainza ORCID, J. E. Rodrigues ORCID, L. Martínez ORCID, E. Céspedes ORCID, N. M. Nemes ORCID, J. L. Martínez ORCID, J. A. Alonso ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A rapid high-pressure preparation method (3.5 GPa) yields FexTi2S4 Heideite-type phase. Magnetism offers a complex scenario with AFM to FM-like interactions. The magnetocaloric effect yields significant entropy and relative cooling power.