Published in
Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 17(10), p. 6857-6865, 2022
DOI: 10.1039/d2tc00653g
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The structural evolution, optical gap, and thermoelectric properties of the RbPb<sub>2</sub>Br<sub>5</sub> layered halide, prepared by mechanochemistry
Journal article published in 2022 by
Carmen Abia,
Carlos A. López 
,
Javier Gainza ,
João Elias F. S. Rodrigues ,
Mateus M. Ferrer,
N. M. Nemes ,
Oscar J. Dura ,
José L. Martínez ,
María T. Fernández-Díaz ,
Consuelo Álvarez-Galván ,
Gergely Németh,
Katalin Kamarás,
François Fauth ,
José A. Alonso
,
Javier Gainza ,
João Elias F. S. Rodrigues ,
Mateus M. Ferrer,
N. M. Nemes ,
Oscar J. Dura ,
José L. Martínez ,
María T. Fernández-Díaz ,
Consuelo Álvarez-Galván ,
Gergely Németh,
Katalin Kamarás,
François Fauth ,
José A. Alonso
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Abstract
RbPb2Br5 was studied by SXRD and NPD data from 15 to 573 K, yielding information on Rb–Br and Pb–Br chemical bonds. The electron lone pair of Pb2+ is visualized. Photoluminescence excitation and emission spectra suggest applications in photovoltaics.