Published in
Royal Society of Chemistry, Inorganic Chemistry Frontiers, 10(8), p. 2505-2517, 2021
DOI: 10.1039/d1qi00314c
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Electron belt-to-σ-hole switch of noncovalently bound iodine(i) atoms in dithiocarbamate metal complexes
Journal article published in 2021 by
Lev E. Zelenkov 
,
Anastasiya A. Eliseeva ,
Sergey V. Baykov ,
Vitalii V. Suslonov ,
Bartomeu Galmés,
Antonio Frontera ,
Vadim Y.-U. Kukushkin ,
Daniil M. Ivanov ,
Nadezhda A. Bokach
,
Anastasiya A. Eliseeva ,
Sergey V. Baykov ,
Vitalii V. Suslonov ,
Bartomeu Galmés,
Antonio Frontera ,
Vadim Y.-U. Kukushkin ,
Daniil M. Ivanov ,
Nadezhda A. Bokach
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Abstract
The nature of metals in the isostructural series of dithiocarbamate complexes affects the electron belt-to-σ-hole switch of noncovalently bound iodine(i) leading to either semicoordination, or halogen bonding.