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Royal Society of Chemistry, Inorganic Chemistry Frontiers, 12(9), p. 2869-2879, 2022

DOI: 10.1039/d2qi00438k

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Inorganic–organic {d<sub>z<sup>2</sup></sub>-M<sup>II</sup>S<sub>4</sub>}⋯π-hole stacking in reverse sandwich structures: the case of cocrystals of group 10 metal dithiocarbamates with electron-deficient arenes

Journal article published in 2022 by Lev E. Zelenkov ORCID, Anastasiya A. Eliseeva ORCID, Sergey V. Baykov ORCID, Daniil M. Ivanov, Alina I. Sumina ORCID, Rosa M. Gomila ORCID, Antonio Frontera ORCID, Vadim Y.-U. Kukushkin ORCID, Nadezhda A. Bokach ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The {dz2-MIIS4} (M = Ni, Pd, Pt) moieties function as integrated five-center acceptors toward a π-hole of an electron-deficient arene furnishing the reverse sandwich structures.