Published in
Royal Society of Chemistry, Dalton Transactions, 28(50), p. 9709-9718, 2021
DOI: 10.1039/d1dt01599k
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Luminescent gold–thallium derivatives with a pyridine-containing 12-membered aza-thioether macrocycle
Journal article published in 2021 by
Francesco Caddeo 
,
Vanesa Fernández-Moreira ,
Massimiliano Arca ,
Anna Pintus,
Antonio Laguna,
Vito Lippolis ,
M. Concepción Gimeno
,
Vanesa Fernández-Moreira ,
Massimiliano Arca ,
Anna Pintus,
Antonio Laguna,
Vito Lippolis ,
M. Concepción Gimeno
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Abstract
The heterometallic TlI/AuI complex {[Au(C6F5)2Tl]2(L)}n has an unprecedented polymeric structural motif with a metallic pseudo-rhombic Au2Tl2 core that repeats itself to form zig-zag polymers and shows a thermochromic behaviour.