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Royal Society of Chemistry, Dalton Transactions, 41(50), p. 14542-14546, 2021

DOI: 10.1039/d1dt02637b

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Same ligand, three first-row metals: comparing M-amido bifunctional reactivity (Mn, Fe, Co)

Journal article published in 2021 by Matthew R. Elsby ORCID, Scott Y. H. Kim, Stephan N. Steinmann ORCID, R. Tom Baker ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Three analogous M(SNS)2 complexes with bifunctional amido donors were used to compare reactivity across the base metals (M = Mn, Fe, Co). Experimental studies support DFT findings in which only the Mn complex can facilitate bifunctional H2 activation.