Published in
Royal Society of Chemistry, Polymer Chemistry, 23(14), p. 2820-2828, 2023
DOI: 10.1039/d3py00230f
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Synthesis of phase-separated super-H-shaped triblock architectures: poly(l-lactide) grafted from telechelic polyisoprene
Journal article published in 2023 by
Moritz Meier-Merziger 
,
Marcel Fickenscher,
Frank Hartmann ,
Björn Kuttich,
Tobias Kraus,
Markus Gallei ,
Holger Frey
,
Marcel Fickenscher,
Frank Hartmann ,
Björn Kuttich,
Tobias Kraus,
Markus Gallei ,
Holger Frey
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Abstract
A general approach for super-H-shaped block copolymers based on bifunctional carbanionic polymerization, epoxide termination and lactone ROP is introduced. TEM and SAXS confirmed microphase separation of (PLLA)3-b-PI-b-(PLLA)3 triblock structures.