Published in
Royal Society of Chemistry, Chemical Communications, 42(58), p. 6255-6258, 2022
DOI: 10.1039/d2cc00847e
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Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters
Journal article published in 2022 by
Anurag Singh 
,
Aaron Torres-Huerta ,
Tom Vanderlinden,
Nathan Renier ,
Luis Martínez-Crespo ,
Nikolay Tumanov ,
Johan Wouters ,
Kristin Bartik ,
Ivan Jabin ,
Hennie Valkenier
,
Aaron Torres-Huerta ,
Tom Vanderlinden,
Nathan Renier ,
Luis Martínez-Crespo ,
Nikolay Tumanov ,
Johan Wouters ,
Kristin Bartik ,
Ivan Jabin ,
Hennie Valkenier
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Abstract
A calix[6]arene with three preorganised halogen bond donating groups gives >100-fold selectivity for Cl− uniport over HCl symport, in contrast to analogous compounds with strong hydrogen bond donating groups.