Carbon dioxide uptake by [Cu(bpca)]+: synthesis, crystal structure, and magnetic properties of {[Na(H2O)2][Cu2(bpca)2(CO3)(HCO3)]}n [Hbpca = bis(2-pyridylcarbonyl)amide]

da Silva, Rafaela M. R.; Rosa, Iara M. L.; Oliveira, Willian X. C.; Alves, Odivaldo C.; Santos, Evelyn C. S.; Garcia, Flávio; Silva Junior, Henrique C.; Ferreira, Glaucio B.; Guedes, Guilherme P.; do Pim, Walace D.; Julve, Miguel; Marinho, Maria Vanda

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Royal Society of Chemistry, New Journal of Chemistry, 3(47), p. 1066-1075, 2023

DOI: 10.1039/d2nj05268g

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Carbon dioxide uptake by [Cu(bpca)]+: synthesis, crystal structure, and magnetic properties of {[Na(H2O)2][Cu2(bpca)2(CO3)(HCO3)]}n [Hbpca = bis(2-pyridylcarbonyl)amide]

Journal article published in 2023 by Rafaela M. R. da Silva

, Iara M. L. Rosa

, Willian X. C. Oliveira

, Odivaldo C. Alves

, Evelyn C. S. Santos

, Flávio Garcia

, Henrique C. Silva Junior

, Glaucio B. Ferreira

, Guilherme P. Guedes

, Walace D. do Pim

, Miguel Julve

, Maria Vanda Marinho

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Abstract

Carbon dioxide fixation by [Cu(bpca)(H₂O)]²⁺ resulted in a chain having CO₃²⁻ and HCO₃⁻ as ligands that shows a weak intrachain ferromagnetic interaction.

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Carbon dioxide uptake by [Cu(bpca)]<sup>+</sup>: synthesis, crystal structure, and magnetic properties of {[Na(H<sub>2</sub>O)<sub>2</sub>][Cu<sub>2</sub>(bpca)<sub>2</sub>(CO<sub>3</sub>)(HCO<sub>3</sub>)]}<sub>n</sub> [Hbpca = bis(2-pyridylcarbonyl)amide]

Abstract