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Royal Society of Chemistry, Dalton Transactions, 45(52), p. 16974-16983, 2023

DOI: 10.1039/d3dt01122d

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1,2-Azolylamidino ruthenium(ii) complexes with DMSO ligands: electro- and photocatalysts for CO<sub>2</sub> reduction

Journal article published in 2023 by Murphy Jennings, Elena Cuéllar, Ariadna Rojo, Sergio Ferrero ORCID, Gabriel García-Herbosa ORCID, John Nganga, Alfredo M. Angeles-Boza ORCID, Jose M. Martín-Alvarez ORCID, Daniel Miguel ORCID, Fernando Villafañe ORCID
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Abstract

Ru(ii) 1,2-azolylamidino-DMSO complexes are herein described. Their electrochemical behavior in CO2 media is consistent with CO2 electrocatalyzed reduction, whereas photocatalytic CO2 reduction experiments lead to CO and trace amounts of formate.