Published in
Royal Society of Chemistry, Dalton Transactions, 45(52), p. 16974-16983, 2023
DOI: 10.1039/d3dt01122d
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1,2-Azolylamidino ruthenium(ii) complexes with DMSO ligands: electro- and photocatalysts for CO<sub>2</sub> reduction
Journal article published in 2023 by
Murphy Jennings,
Elena Cuéllar,
Ariadna Rojo,
Sergio Ferrero 
,
Gabriel García-Herbosa ,
John Nganga,
Alfredo M. Angeles-Boza ,
Jose M. Martín-Alvarez ,
Daniel Miguel ,
Fernando Villafañe
,
Gabriel García-Herbosa ,
John Nganga,
Alfredo M. Angeles-Boza ,
Jose M. Martín-Alvarez ,
Daniel Miguel ,
Fernando Villafañe
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Abstract
Ru(ii) 1,2-azolylamidino-DMSO complexes are herein described. Their electrochemical behavior in CO2 media is consistent with CO2 electrocatalyzed reduction, whereas photocatalytic CO2 reduction experiments lead to CO and trace amounts of formate.