Published in
Royal Society of Chemistry, Chemical Communications, 98(59), p. 14536-14539, 2023
DOI: 10.1039/d3cc04969h
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Synthesis of core–shell polymer particles in supercritical carbon dioxide via iterative monomer addition
Journal article published in 2023 by
Kristoffer Kortsen 
,
Morgan Reynolds-Green ,
Bradley Hopkins,
Alison McLellan,
Matthew J. Derry ,
Paul D. Topham ,
Jeremy J. Titman ,
Daniel J. Keddie ,
Vincenzo Taresco ,
Steven M. Howdle
,
Morgan Reynolds-Green ,
Bradley Hopkins,
Alison McLellan,
Matthew J. Derry ,
Paul D. Topham ,
Jeremy J. Titman ,
Daniel J. Keddie ,
Vincenzo Taresco ,
Steven M. Howdle
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Abstract
Synthesis of polymer core–shell particles via seeded dispersion polymerisation in scCO2 is achieved via iterative addition of a shell monomer to a pre-prepared polymer core. After depressurising the reactor, the products are isolated as dry powders.