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Royal Society of Chemistry, Organic Chemistry Frontiers, 22(10), p. 5610-5615, 2023

DOI: 10.1039/d3qo00742a

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Construction of 1,2-cis rhamnosidic linkages and synthesis of core tetrasaccharide repeating unit of Streptococcus pneumoniae serotype 23F

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

An effective ZnI2-mediated 1,2-cis-l-rhamnosylation strategy was achieved by employing a 2,3-O-(o-xylylene) rhamnose donor, and applied to assemble the core repeating tetrasaccharide unit of the S. pneumoniae 23F capsule polysaccharide.