Royal Society of Chemistry, Organic and Biomolecular Chemistry, 24(21), p. 5098-5103, 2023
DOI: 10.1039/d3ob00817g
Full text: Unavailable
Site-selective oxidation of unprotected saccharides, followed by treatment of the corresponding trityl hydrazone with t-Bu hypochlorite, gives a chloro-azo intermediate that can be substituted to give deoxythio sugars. This allows a protecting group-free synthesis of thioglycosides.