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Royal Society of Chemistry, Organic and Biomolecular Chemistry, 24(21), p. 5098-5103, 2023

DOI: 10.1039/d3ob00817g

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Site-selective introduction of thiols in unprotected glycosides

Journal article published in 2023 by Niels R. M. Reintjens ORCID, Martin D. Witte ORCID, Adriaan J. Minnaard ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Site-selective oxidation of unprotected saccharides, followed by treatment of the corresponding trityl hydrazone with t-Bu hypochlorite, gives a chloro-azo intermediate that can be substituted to give deoxythio sugars. This allows a protecting group-free synthesis of thioglycosides.