Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 42(24), p. 26134-26143, 2022
DOI: 10.1039/d2cp03544h
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Helical versus linear Jahn–Teller distortions in allene and spiropentadiene radical cations
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Abstract
The allene radical cation can be stabilized both by Jahn–Teller distortion of the bond lengths and by torsion of the end-groups.