Published in
Royal Society of Chemistry, Nanoscale, 19(14), p. 7332-7340, 2022
DOI: 10.1039/d2nr00702a
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Unravelling the key factors in the chlorine-promoted epoxidation of ethylene over a silver–copper oxide nanocatalyst
Journal article published in 2022 by
Miguel Urbiztondo,
Adrian Ramirez 
,
Jose L. Hueso ,
Jesus Santamaria,
A. Rabdel Ruiz-Salvador ,
Said Hamad
,
Jose L. Hueso ,
Jesus Santamaria,
A. Rabdel Ruiz-Salvador ,
Said Hamad
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Abstract
This work explores the enhanced selectivity of a silver–copper oxide nanocatalyst towards the epoxidation of ethylene. Experimental and DFT calculations suggest the co-existence of indirect and direct pathways and the influence of desorption rates.