Published in
Royal Society of Chemistry, Dalton Transactions, 20(50), p. 7078-7084, 2021
DOI: 10.1039/d1dt00765c
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Coordination capacity of Keggin anions as polytopic ligands: case study of [VNb12O40]15−
Journal article published in 2021 by
Anna A. Mukhacheva 
,
Victoria V. Volcheck ,
Dmitry G. Sheven ,
Vadim V. Yanshole ,
Nikolay B. Kompankov,
Mohamed Haouas ,
Pavel A. Abramov ,
Maxim N. Sokolov
,
Victoria V. Volcheck ,
Dmitry G. Sheven ,
Vadim V. Yanshole ,
Nikolay B. Kompankov,
Mohamed Haouas ,
Pavel A. Abramov ,
Maxim N. Sokolov
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Abstract
[VNb12O40]15− polytopic ligand can coordinate to up to five {(C6H6)Ru}2+ groups. Combined analytical separation tools together with 1H DOSY NMR were firstly applied to the solution studies of polyoxoniobate based complexes.