Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 20(23), p. 11649-11662, 2021
DOI: 10.1039/d1cp01255j
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Mechanisms of methyl formate production during electron-induced processing of methanol–carbon monoxide ices
Journal article published in 2021 by
Fabian Schmidt 
,
Petra Swiderek ,
Tarek Scheele ,
Jan H. Bredehöft
,
Petra Swiderek ,
Tarek Scheele ,
Jan H. Bredehöft
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Abstract
A novel mechanism is proposed for the electron-induced production of methyl formate from CO and CH3OH which is relevant for interstellar ice chemistry. A key-step in this reaction is the formation of an intermediate CH3OCO radical.