Published in
Royal Society of Chemistry, Dalton Transactions, 3(51), p. 885-897, 2022
DOI: 10.1039/d1dt03959h
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The Influence of Different Carbonate Ligands on the Hydrolytic Stability and Reduction of Platinum(IV) Prodrugs
Journal article published in 2022 by
Shu Chen,
Ka-Yan Ng,
Qiyuan Zhou,
Houzong Yao,
Zhiqin Deng 
,
Man-Kit Tse,
Guangyu Zhu
,
Man-Kit Tse,
Guangyu Zhu
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Abstract
The hydrolysis and reduction of Pt(iv) carbonates depend on the electron-withdrawing ability of the carbonates and the nature of the opposite axial ligands. The hydrolytic process for Pt(iv) carbonates proceeds by attacking the carbonyl carbon.