Published in
Royal Society of Chemistry, Chemical Communications, 93(57), p. 12456-12459, 2021
DOI: 10.1039/d1cc05610g
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Steric control of sorting regimes in self-assembled cages
Journal article published in 2021 by
Samuel E. Walker 
,
Stephanie A. Boer,
Thomas Malcomson ,
Martin J. Paterson ,
Kellie L. Tuck ,
David R. Turner
,
Stephanie A. Boer,
Thomas Malcomson ,
Martin J. Paterson ,
Kellie L. Tuck ,
David R. Turner
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Abstract
Self-sorting regimes are controlled by adjusting steric interactions in self-assembled coordination cages and equilibration followed by HPLC. Statistical or biased distributions can be obtained, including isolation of a single heteroleptic species.