Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 38(23), p. 21532-21543, 2021
DOI: 10.1039/d1cp03033g
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Proton in the ring: spectroscopy and dynamics of proton bonding in macrocycle cavities
Journal article published in 2021 by
Francisco Gámez 
,
Juan R. Avilés-Moreno ,
Giel Berden ,
Jos Oomens,
Bruno Martínez-Haya
,
Juan R. Avilés-Moreno ,
Giel Berden ,
Jos Oomens,
Bruno Martínez-Haya
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Abstract
Protons confined in the ring cavities of crown ethers form dynamic proton bonds that migrate to varying pairs of coordinating atoms, at a rate depending on electronegativity and on the flexibility of the macrocycle backbone.