Published in
Royal Society of Chemistry, Dalton Transactions, 37(50), p. 12821-12825, 2021
DOI: 10.1039/d1dt02589a
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The Electrochemical Reduction of a Flexible Mn(II) Salen-Based Metal-Organic Framework
Journal article published in 2021 by
Marcello B. Solomon 
,
Carol Hua ,
Bun Chan ,
Tamara L. Church,
Seth M. Cohen ,
Clifford P. Kubiak ,
Katrina A. Jolliffe ,
Deanna Michelle D'Alessandro
,
Carol Hua ,
Bun Chan ,
Tamara L. Church,
Seth M. Cohen ,
Clifford P. Kubiak ,
Katrina A. Jolliffe ,
Deanna Michelle D'Alessandro
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Abstract
A salen-based MOF is reported that is stable to desolvation and exhibits a crystalline-to-amorphous transition. The framework is stable to a one-electron reduction, which is characterised spectroelectrochemically and using computational calculations.