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Royal Society of Chemistry, Dalton Transactions, 14(50), p. 5011-5022, 2021

DOI: 10.1039/d1dt00881a

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Stepwise collapse of a giant pore metal–organic framework

Journal article published in 2021 by Adam F. Sapnik ORCID, Duncan N. Johnstone ORCID, Sean M. Collins ORCID, Giorgio Divitini ORCID, Alice M. Bumstead ORCID, Christopher W. Ashling ORCID, Philip A. Chater ORCID, Dean S. Keeble ORCID, Timothy Johnson ORCID, David A. Keen ORCID, Thomas D. Bennett ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Defect engineering is used to augment the porosity of MIL-100. Incorporation of defects leads to structural collapse and ultimately causes amorphisation. Pair distribution function analysis reveals a stepwise collapse of the hierarchical structure.