Published in
Royal Society of Chemistry, Chemical Communications, 22(57), p. 2732-2735, 2021
DOI: 10.1039/d0cc07884k
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Constructing an unprecedented {Mn<sup>II</sup><sub>38</sub>} matryoshka doll with a [Mn<sub>18</sub>(CO<sub>3</sub>)<sub>9</sub>] inorganic core and magnetocaloric effect
Journal article published in 2021 by
Tai-Xue Wu,
Ye Tao,
Qiu-Ju He,
Hai-Ye Li,
He-Dong Bian 
,
Fu-Ping Huang
,
Fu-Ping Huang
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Abstract
An unprecedented [Mn18(CO3)9] inorganic core and [Mn20] metal–organic periphery composed the largest homometallic single-valence {MnII38} aggregate with a four-shells matryoshka doll that displays a significant magnetocaloric effect (MCE).