Enhancement of the coordinating flexibility in a Schiff–Mannich combo ligand: forced generation of a new NiII–Ophenoxo–LnIII–Oalkoxo–LnIII array (Ln = Gd, Tb, Dy and Ho)

Royal Society of Chemistry, New Journal of Chemistry, 11(45), p. 5258-5265, 2021

Journal article published in 2021 by Riya Bag

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A series of 3d–4f complexes, containing rare NiLn₂O₄ topology, were synthesized by designing a new type of combo Schiff base–Mannich ligand.

Enhancement of the coordinating flexibility in a Schiff–Mannich combo ligand: forced generation of a new Ni<sup>II</sup>–O<sub>phenoxo</sub>–Ln<sup>III</sup>–O<sub>alkoxo</sub>–Ln<sup>III</sup> array (Ln = Gd, Tb, Dy and Ho)