Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 8(9), p. 4898-4906, 2021
DOI: 10.1039/d0ta09462e
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Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage
Journal article published in 2021 by
Jelle Wieme 
,
Veronique Van Speybroeck
,
Veronique Van Speybroeck
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Abstract
Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.