Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 5(23), p. 3656-3667, 2021
DOI: 10.1039/d0cp06080a
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Structure and Excited-State Dynamics of Dimeric Copper(I) photosensitizers Investigated by Time-resolved X-ray and Optical Transient Absorption Spectroscopy
Journal article published in 2021 by
Lucia Velasco,
Leonel Llanos,
Pedro Levin 
,
Andres Vega ,
Jin Yu,
Xiaoyi Zhang,
Luis A. Lemus ,
Daniel Aravena ,
Dooshaye Moonshiram
,
Andres Vega ,
Jin Yu,
Xiaoyi Zhang,
Luis A. Lemus ,
Daniel Aravena ,
Dooshaye Moonshiram
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Abstract
Three homoleptic Cu(i) dimeric photosensitizers are studied through ultrafast X-ray and optical absorption spectroscopy. The complexes show distinct excited state lifetimes, due to the solvent type and spacers' flexibilities between the Cu centres.