Published in
Royal Society of Chemistry, Chemical Communications, 7(57), p. 875-878, 2021
DOI: 10.1039/d0cc06983c
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Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO<sub>2</sub>
Journal article published in 2021 by
Philipp Zimmermann,
Alexander F. R. Kilpatrick 
,
Deniz Ar,
Serhiy Demeshko,
Beatrice Cula ,
Christian Limberg
,
Deniz Ar,
Serhiy Demeshko,
Beatrice Cula ,
Christian Limberg
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Abstract
Even though β-diketiminato nickel(ii) bromide and cobaltocene have nearly identical redox potentials the corresponding electron transfer complex can be crystallised from the equilibrium and activates CO2 to form a mononuclear nickel(ii) carbonate.