Published in
Royal Society of Chemistry, Inorganic Chemistry Frontiers, 4(8), p. 1102-1110, 2021
DOI: 10.1039/d0qi01140a
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Insight into the structure–property relationship of UO<sub>2</sub>nanoparticles
Journal article published in 2021 by
Evgeny Gerber 
,
Anna Y.-U. Romanchuk ,
Stephan Weiss ,
Stephen Bauters ,
Bianca Schacherl ,
Tonya Vitova ,
René Hübner ,
Salim Shams Aldin Azzam,
Dirk Detollenaere,
Dipanjan Banerjee ,
Sergei M. Butorin ,
Stepan N. Kalmykov ,
Kristina O. Kvashnina
,
Anna Y.-U. Romanchuk ,
Stephan Weiss ,
Stephen Bauters ,
Bianca Schacherl ,
Tonya Vitova ,
René Hübner ,
Salim Shams Aldin Azzam,
Dirk Detollenaere,
Dipanjan Banerjee ,
Sergei M. Butorin ,
Stepan N. Kalmykov ,
Kristina O. Kvashnina
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Abstract
We show that the structural and electronic properties of UO2NPs (2–3 nm) are similar to those of bulk UO2under inert conditions, with U(iv) as the dominating oxidation state, though NPs oxidize with time and under the X-ray beam.