Published in
Royal Society of Chemistry, Chemical Communications, 5(57), p. 576-579, 2021
DOI: 10.1039/d0cc07540j
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Arylene–hexaynylene and –octaynylene macrocycles: extending the polyyne chains drives self-association by enhanced dispersion force
Journal article published in 2021 by
Shin-Ichiro Kato 
,
Ryo Kumagai,
Tsukasa Abe,
Chisa Higuchi,
Yoshihito Shiota ,
Kazunari Yoshizawa ,
Nobutaka Takahashi,
Koji Yamamoto ,
Md Zakir Hossain,
Kazuhiro Hayashi,
Takashi Hirose ,
Yosuke Nakamura
,
Ryo Kumagai,
Tsukasa Abe,
Chisa Higuchi,
Yoshihito Shiota ,
Kazunari Yoshizawa ,
Nobutaka Takahashi,
Koji Yamamoto ,
Md Zakir Hossain,
Kazuhiro Hayashi,
Takashi Hirose ,
Yosuke Nakamura
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Abstract
We synthesized arylene–alkynylene macrocycles containing hexayne and octayne, which enables quantitative analysis of self-association constants depending on the length of the polyyne chains for the first time.