Published in
Royal Society of Chemistry, Dalton Transactions, 2(50), p. 660-674, 2021
DOI: 10.1039/d0dt03695a
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Electronic and geometric structure effects on one-electron oxidation of first-row transition metals in the same ligand framework
Journal article published in 2020 by
Manuel Boniolo 
,
Petko Chernev ,
Mun Hon Cheah ,
Philipp A. Heizmann,
Ping Huang ,
Sergii I. Shylin ,
Nessima Salhi,
Md Kamal Hossain ,
Arvind K. Gupta,
Johannes Messinger ,
Anders Thapper ,
Marcus Lundberg
,
Petko Chernev ,
Mun Hon Cheah ,
Philipp A. Heizmann,
Ping Huang ,
Sergii I. Shylin ,
Nessima Salhi,
Md Kamal Hossain ,
Arvind K. Gupta,
Johannes Messinger ,
Anders Thapper ,
Marcus Lundberg
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Abstract
The MII to MIII oxidation of base metals in a pentapyridyl ligand framework with an exchangeable apical ligand is studied by electrochemistry, XRD and XAS, and interpreted based on DFT calculations.