Published in
Royal Society of Chemistry, Chemical Communications, 3(57), p. 375-378, 2021
DOI: 10.1039/d0cc07072f
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Synthesis and reactivity of phosphine borohydride compounds
Journal article published in 2020 by
Ramaraj Ayyappan 
,
Yannick Coppel ,
Laure Vendier,
Sundargopal Ghosh ,
Sylviane Sabo-Etienne ,
Sébastien Bontemps
,
Yannick Coppel ,
Laure Vendier,
Sundargopal Ghosh ,
Sylviane Sabo-Etienne ,
Sébastien Bontemps
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Abstract
Strong evidence for non-bonded through space P–B coupling are obtained by close positioning of phosphine and borate moieties. The new species readily release LiH to carbonyl and generate phosphine borane ambiphilic compounds.