Published in
Royal Society of Chemistry, Dalton Transactions, 47(49), p. 17230-17242, 2020
DOI: 10.1039/d0dt03546g
Links
Tools
Photocatalytic hydrogen evolution using a Ru(ii)-bound heteroaromatic ligand as a reactive site
Journal article published in 2020 by
Takuya Sawaki,
Tomoya Ishizuka 
,
Nanase Namura,
Dachao Hong ,
Mayuko Miyanishi,
Yoshihito Shiota,
Hiroaki Kotani ,
Kazunari Yoshizawa ,
Jieun Jung,
Shunichi Fukuzumi ,
Takahiko Kojima
,
Nanase Namura,
Dachao Hong ,
Mayuko Miyanishi,
Yoshihito Shiota,
Hiroaki Kotani ,
Kazunari Yoshizawa ,
Jieun Jung,
Shunichi Fukuzumi ,
Takahiko Kojima
This paper is made freely available by the publisher.
Full text: Download
Published version:
archiving forbidden
Data provided by 
Abstract
A RuII complex with a π-expanded diimine ligand performs photocatalytic H2 evolution and hydrogenation of organic substrates under visible-light irradiation, involving an intermediate with the dihydrogenated ligand; a mechanistic insight into the H2 evolution is also gained.