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Royal Society of Chemistry, Dalton Transactions, 41(49), p. 14584-14591, 2020

DOI: 10.1039/d0dt03415k

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Phosphinoborane interception at magnesium by borane-assisted phosphine-borane dehydrogenation

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Ph2PBH2is generated and trapped on-metal by addition of B(C6F5)3to a β-diketiminato magnesium phospidoborane complex, similar reactivity is meanwhile prevented for the analogous calcium-based system by formation of a stable η6-toluene complex.