Tuning magnetic anisotropy by the π-bonding features of the axial ligands and the electronic effects of gold(i) atoms in 2D {Co(L)2[Au(CN)2]2}nmetal–organic frameworks with field-induced single-ion magnet behaviour

Royal Society of Chemistry, Inorganic Chemistry Frontiers, 23(7), p. 4611-4630, 2020

Journal article published in 2020 by María A. Palacios, Ismael F. Díaz-Ortega, Hiroyuki Nojiri

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Au^I atoms play an important role in determining the anisotropy of Co^II nodes in 2D Au^I–Co^II field-induced SIMs.

Tuning magnetic anisotropy by the π-bonding features of the axial ligands and the electronic effects of gold(i) atoms in 2D {Co(L)<sub>2</sub>[Au(CN)<sub>2</sub>]<sub>2</sub>}<sub>n</sub>metal–organic frameworks with field-induced single-ion magnet behaviour