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Royal Society of Chemistry, Green Chemistry, 6(8), p. 549

DOI: 10.1039/b601984f

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On the active site in heterogeneous palladium selox catalysts

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This paper is available in a repository.

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Abstract

The nature of the active site in the Pd-catalysed aerobic selective oxidation of cinnamyl and crotyl alcohols has been directly probed by bulk and surface X-ray techniques. The importance of high metal dispersions and the crucial role of surface palladium oxide have been identified. © The Royal Society of Chemistry 2006.