Published in
Royal Society of Chemistry, CrystEngComm, 42(22), p. 6979-6982, 2020
DOI: 10.1039/d0ce01272f
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A C(π-hole)···Cl-Zn tetrel interaction driving a metal-organic supramolecular assembly
Journal article published in 2020 by
Carmen Ramirez de Arellano 
,
Rosa Adam,
Rafael Ballesteros-Garrido ,
Belén Abarca,
Rafael Ballesteros ,
Ibon Alcorta ,
Ibon Alkorta,
Jose Elguero,
Emilio Escrivá
,
Rosa Adam,
Rafael Ballesteros-Garrido ,
Belén Abarca,
Rafael Ballesteros ,
Ibon Alcorta ,
Ibon Alkorta,
Jose Elguero,
Emilio Escrivá
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Abstract
A brominated pyrimidinyl triazolopyridine ligand (bptpy) forms a C(π-hole)⋯Cl–Zn tetrel interaction that drives the formation of supramolecular layers through chain assembly in 18 membered metallacycle [(ZnCl2)2(μ-bptpy)2] crystals.