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Royal Society of Chemistry, Chemical Communications, 76(56), p. 11295-11298, 2020
DOI: 10.1039/d0cc05188h
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An Efficient [3+2] Annulation for the Asymmetric Synthesis of Densely-Functionalized Pyrrolidinones and γ-Butenolides
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Abstract
Disclosed here is a new [3+2] annulation of siloxy alkynes that provides robust access to highly enantioenriched, densely-substituted pyrrolidinones and γ-butenolides, whose direct synthesis remains challenging.