Published in
Royal Society of Chemistry, New Journal of Chemistry, 33(44), p. 14171-14179, 2020
DOI: 10.1039/d0nj02328k
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Synthesis of mono/dinuclear rhenium(I) tricarbonyl substituted with 4-mercaptopyridine related ligands: Spectral and theoretical evidence of thiolate/thione interconversion.
Journal article published in 2020 by
Alejandra Gómez 
,
Geraldine Jara,
Erick Flores ,
Tamara Maldonado ,
Fernando Godoy ,
Michelle Muñoz,
Andres Vega ,
Raul Mera-Adasme,
Carlos Silva,
Jorge Pavez
,
Geraldine Jara,
Erick Flores ,
Tamara Maldonado ,
Fernando Godoy ,
Michelle Muñoz,
Andres Vega ,
Raul Mera-Adasme,
Carlos Silva,
Jorge Pavez
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Abstract
κ1-S complexes show solvent-mediated tautomerism. The S–S bridge cleavage in κ1-N derivatives is attributed to the presence of a proton source.