Published in

Royal Society of Chemistry, Organic Chemistry Frontiers, 17(7), p. 2505-2510, 2020

DOI: 10.1039/c9qo01304k

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Enantiodivergent reduction of α-keto amides catalyzed by high valent, chiral oxido-vanadium(v) complexes

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Complementary asymmetric reductions of N-benzyl-α-keto amides were achieved for the first time by an air and moisture stable, reduced form of vanadyl(v) N-salicylidene-t-leucinate with HBPin and HBCat with up to 99% and 90% ee, respectively.