Published in
Royal Society of Chemistry, Chemical Communications, 68(56), p. 9783-9786, 2020
DOI: 10.1039/d0cc03289a
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Selective catalytic 2e–-oxidation of organic substrates by an FeII complex having an N-heterocyclic carbene ligand in water
Journal article published in 2020 by
Hiroto Fujisaki,
Tomoya Ishizuka 
,
Yoshihiro Shimoyama ,
Hiroaki Kotani ,
Yoshihito Shiota ,
Kazunari Yoshizawa ,
Takahiko Kojima
,
Yoshihiro Shimoyama ,
Hiroaki Kotani ,
Yoshihito Shiota ,
Kazunari Yoshizawa ,
Takahiko Kojima
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Abstract
An FeII complex, 1, having a pentadentate ligand with an NHC moiety catalyzes substrate oxidation to afford 2e−-oxidized products with high selectivity by suppression of overoxidation in water.