Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 27(18), p. 5183-5191, 2020
DOI: 10.1039/d0ob00684j
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Selective C–H chalcogenation of thiazoles via thiazol-2-yl-phosphonium salts
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Abstract
Medicinally relevant substituted benzothiazoles and thiazoles are prepared under mild conditions by a regioselective C2–H chalcogenation via preparation of the phosphonium salt and the subsequent reaction with S- and Se-centered nucleophiles.