Published in
Royal Society of Chemistry, Dalton Transactions, 45(49), p. 16404-16418, 2020
DOI: 10.1039/d0dt01383h
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Robust Mn(III) N-pyridylporphyrin-based biomimetic catalysts for hydrocarbon oxidations: Heterogenization on non-functionalized silica gel versus chloropropyl-functionalized silica gel
Journal article published in 2020 by
Victor Hugo Araujo Pinto,
Victor Hugo A. Pinto 
,
Nathalia Kellyne Silva Marinho Falcao ,
Barbara Mariz-Silva ,
Maria Gardennia Fonseca ,
Julio S. Reboucas
,
Nathalia Kellyne Silva Marinho Falcao ,
Barbara Mariz-Silva ,
Maria Gardennia Fonseca ,
Julio S. Reboucas
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Abstract
Simple neutral and cationic Mn porphyrins were immobilized on ordinary chromatographic silica or chloropropyl-functionalized silica supports to yield efficient and reusable biomimetic catalysts for C–H activation and oxyfunctionalization of alkanes.