Published in
Royal Society of Chemistry, Dalton Transactions, 28(49), p. 9564-9567, 2020
DOI: 10.1039/d0dt00367k
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Intramolecular C(sp2)–C (sp2) bond formation between phenanthroline and β-diketone thiosemicarbazones in PtII complexes: crystal structures and computational studies
Journal article published in 2020 by
Ana C. R. Gonçalves,
Andressa R. Rettondin,
Carolina G. Oliveira 
,
Antonio O. T. Patrocinio ,
Antonio E. H. Machado ,
Victor M. Deflon ,
Ulrich Abram ,
Pedro I. S. Maia
,
Antonio O. T. Patrocinio ,
Antonio E. H. Machado ,
Victor M. Deflon ,
Ulrich Abram ,
Pedro I. S. Maia
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Abstract
[PtCl2(phen)] reacts with β-diketone derived thiosemicarbazones leading to an intramolecular C–C coupling and formation of tetracoordinated N,N,N,S-chelates [PtII(phenLR)].